山东金伯利岩中榄橄石的研究          下载免费PDF全文

董振信 《岩石矿物学杂志》1991,(4)

本文百次研究了山东金伯利岩中橄榄石的产状、含量、大小、世代、形态、颜色、环带、矿物包体、折光率、2V、化学成分、端员组分特征及红外光谱和穆斯堡尔谱特征,并分析研究了橄榄石的成因。指出了无色—浅绿色的、含MgO、Cr2O3、NiO高的橄榄石是找金刚石矿的指示性矿物。  相似文献   

山东金伯利岩中橄榄石的研究   总被引：1，自引：0，他引：1  

董振信 《岩石矿物学杂志》1991,10(4):354-362

本文首次研究了山东金伯利岩中橄榄石的产状、含量、大小、世代、形态、颜色、 环带、矿物包体、折光率、2V、化学成分、端员组分特征及红外光谱和穆斯堡尔谱特征，并分 析研究了橄榄石的成因。指出了无色一浅绿色的、含MgO、Cr2O3. Ni0高的橄榄石是找金刚石 矿的指示性矿物。  相似文献   

Thermodynamic modeling of post-entrapment crystallization in igneous phases     

Victor C. Kress  Mark S. Ghiorso 《Journal of Volcanology and Geothermal Research》2004,137(4):247-260

Inclusions of quenched silicate liquid in igneous phenocryst phases represent important windows into the pre-eruption chemistry of volcanic rocks. Melt inclusions are subject to a variety of potential modifications after entrapment, which obscure the connection between final inclusion composition, and entrapment conditions. We concentrate on the effects of post-entrapment crystallization (PEC) in the cooling inclusion. PEC is neither an isobaric nor an isochoric process. Pressure decreases between 2 and 27 bars per degree of cooling, depending on the chemistry of melt and host and on the degree of PEC. In the equilibrium case, between about 50% and 65% of this pressure effect is due to thermal expansivity of the liquid, 10–35% from thermal expansivity of the host, and 5–40% from mass transfer between the inclusion and host. This complicates the application of simple element-partitioning schemes for back-calculating the effects of post-entrapment crystallization except in the simplest cases. We present a thermodynamic algorithm for PEC correction. This method is based on the self-consistent thermodynamic model set used in the MELTS software package. The algorithm moves backward through the PEC process, incrementally adding equilibrium crystal composition to the liquid while accounting for consequent variations in pressure and oxygen fugacity. Entrapment conditions are assumed to have been reached when the instantaneous liquidus solid composition most closely matches that of the bulk host crystal. Besides giving information on the degree of PEC and initial inclusion composition, the proposed algorithm can provide constraints on the pressure, temperature and oxygen fugacity at the time of entrapment. Olivine- and orthopyroxene-hosted inclusions from Popocatépetl, Mexico help constrain pre-eruption conditions for mixed magmas from recent eruptive products. Feldspar-hosted inclusions from Satsuma-Iwojima, Japan suggest that these magmas were substantially undersaturated with respect to supercritical vapor phase at the time of entrapment and underwent on the order of 29% post-entrapment crystallization. Quartz-hosted inclusions can potentially be employed in more silicic compositions, but this will require refinement of existing thermodynamic models.  相似文献   

Experimental Study on the Solubility of Cr^2 in Olivine,Orthopyroxene and Spinel Solid Solutions     

Li Jianping  Hugh St. C. O’Neill  Friedrich Seifert 《中国地球化学学报》1997,16(2):139-147

Experiments have been performed on the system MgO-SiO2-Cr-O at 0-2.88 GPa and 1100-1450℃,focusing on the stability of Cr^2 in olivine(O1),orthopyroxene(Opx) and spinel(Sp) and its partitioning between these phases.Analytical reagent grade chemicals,MgO,SiO2,Cr2O3.and Cr were used to make starting mixtures.Excess Cr(50%) was then added in these mixtures to ensure that the resultant phases were in equilibrium with the metal Cr.Flux of BaO B2O3(%) was added for facilitating experimental equilibrium and crystal growth.Cr was used as capsule material.All phases in the product were identified by X-ray and analyzed by electron microprobe,The contents of CrO in the different phases(O1,Opx and Sp)were calculated according to stoichiometry.The obtained results of calculation indicate that Cr^3 in Ol and Opx is negligible.The experimental results show;(a) with increasing temperature and decreasing pressure,Cr^2 solubility in Ol,Opx and Sp increases;(b) with in creasing temperature,the partitioning coefficient of Mg and Cr^2 between Ol and Opx decreases,that between Opx and Sp increases,and that between Ol and Sp remains almost unchanged;(c) the effect of pressure on all partitioning coefficients is negligible.  相似文献   

Mg-Cr~(2+)橄揽石、辉石和尖晶石的晶胞参数测定及Cr~(2+)在各晶体结构中的占位     

李建平  HughSt．C．O’Neill 《矿物学报》1995,(4)

本文用Mg－Cr2+做榄石、辉石、尖晶石的粉晶X射线衍射数据，采取“整体图谱最小二乘Rietveld”方法计算了上述矿物的晶胞参数和摩尔体积，并对Cr2+在各晶体结构中的占位情况进行了研究。结果显示，各矿物的晶胞参数随含Cr2+量的增大而增大。据Vegard定律，推算出各端元组分铬橄榄石（Cr2SiO1）、铬辉石（Cr2SiO2O6）及立方铬尖晶石（Cr3O4）的摩尔体积分别为47．7，68．0，44．9cm3。精化结构参数指示，在橄榄石中，Cr2+随机分配在两个八面体（M1，M2）位置；在辉石中，Cr2+优先选择八面体M2位置；在尖晶石中，Cr2+占置四面体位置。这种晶体内离子分配可从离子半径差别或晶体场稳定能大小得到解释。  相似文献   

橄榄石单晶体高温蠕变   总被引：3，自引：0，他引：3  

金振民 《地球科学》1993,18(1):11-19

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福建明溪大洋窠幔源包体橄榄石的位错结构特征          下载免费PDF全文

董火根  闵茂中  张富生  洪建明 《岩石矿物学杂志》1993,12(1):45-50

本文介绍了采用透射电子显微镜观察研究福建明溪大洋窠上第三系玻基玄武岩中的包体橄榄石的位错结构。研究表明,该地幔源包体橄榄石中存在位错壁、自由位错、位错弓弯和位错环等,它们是该橄榄石在上地幔的高温低应力条件下发生复杂蠕变的产物。根据该地包体橄榄石中自由位错密度(统计值为2.0×10~8cm~(-2)和共生辉石的化学成分,估算出福建明溪大洋窠玻基玄武岩中幔源包体的变形条件为:温度(T)为1070℃;压力(P)为2480MPa;深度(Z)为79.3km;流变应力(σ_1-σ_3)为136MPa;流变速率(ε)为7.6×10~(-13)s~(-1);粘稠度(η)为0.8×10~(20)poise。  相似文献   

独立产出的钛铁晶石的发现及地质意义     

马志新 《矿物学报》1990,10(3):273-277,T001

湖北省均县地区的钛铁晶石是独立产出于含铁辉石岩中,不与钛磁铁矿相连生。通过能谱分析和扫描电镜分析,详细研究了该类产状钛铁晶石的化学元素组成,显微结构特征以及矿物的成因等。  相似文献   

Thermal diffusivity of olivine under upper mantle conditions   总被引：1，自引：0，他引：1  

Tomoo Katsura 《Geophysical Journal International》1995,122(1):63-69

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Mineralogy and petrology of Al-rich objects and amoeboid olivine aggregates in the CH carbonaceous chondrite North West Africa 739     

Alexander N. Krot  Michael I. Petaev  Klaus Keil 《Chemie der Erde / Geochemistry》2006,66(1):57-76

The aluminum-rich (>10 wt% Al₂O₃) objects in the CH carbonaceous chondrite North West Africa (NWA) 739 include Ca,Al-rich inclusions (CAIs), Al-rich chondrules, and isolated mineral grains (spinel, plagioclase, glass). Based on the major mineralogy, 54 refractory inclusions found in about 1 cm² polished section of NWA 739 can be divided into hibonite-rich (16%), grossite-rich (26%), melilite-rich (28%), spinel-pyroxene-rich (16%) CAIs, and amoeboid olivine aggregates, (AOA's, 17%). Most CAIs are rounded, 25–185 μm (average=70 μm) in apparent diameter, contain abundant, tiny perovskite grains, and typically surrounded by a single- or double-layered rim composed of melilite and/or Al-diopside; occasionally, layers of spinel+hibonite and forsterite are observed. The AOAs are irregularly shaped, 100–250 μm (average=175 μm) in size, and consist of forsterite, Fe,Ni-metal, and CAIs composed of Al-diopside, anorthite, and minor spinel. One AOA contains compact, rounded melilite-spinel-perovskite CAIs and low-Ca pyroxene replacing forsterite. The Al-rich (>10 wt% bulk Al₂O₃) chondrules are divided into Al-diopside-rich and plagioclase-rich. The Al-diopside-rich chondrules, 50–310 μm (average=165 μm) in apparent diameter, consist of Al-diopside, skeletal forsterite, spinel, ±Al-rich low-Ca pyroxene, and ±mesostasis. The plagioclase-rich chondrules, 120–455 μm (average=285 μm) in apparent diameter, are composed of low-Ca and high-Ca pyroxenes, forsterite, anorthitic plagioclase, Fe,Ni-metal nodules, and mesostasis. The isolated spinel occurs as coarse, 50–125 μm in size, subhedral grains, which are probably the fragments of Al-diopside chondrules. The isolated plagioclase grains are too coarse (60–120 μm) to have been produced by disintegration of chondrules or CAIs; they range in composition from nearly pure anorthite to nearly pure albite; their origin is unclear. The Al-rich objects show no evidence for Fe-alkali metasomatic or aqueous alteration; the only exception is an Al-rich chondrule fragment with anorthite replaced by nepheline. They are texturally and mineralogically similar to those in other CH chondrites studied (Acfer 182, ALH85085, PAT91467, NWA 770), but are distinct from the Al-rich objects in other chondrite groups (CM, CO, CR, CV). The CH CAIs are dominated by very refractory minerals, such as hibonite, grossite, perovskite and gehlenitic melilite, and appear to have experienced very low degrees of high-temperature alteration reactions. These include replacement of grossite by melilite, of melilite by anorthite, diopside, and spinel, and of forsterite by low-Ca pyroxene. Only a few CAIs show evidence for melting and multilayered Wark-Lovering rims. These observations may suggest that CH CAIs experienced rather simple formation history and escaped extensive recycling. In order to preserve the high-temperature mineral assemblages, they must have been efficiently isolated from the hot nebular region, like some chondrules and the zoned Fe,Ni-metal grains in CH chondrites.  相似文献